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Very few synthetic operations in Organic Chemistry match the import- ance of the oxidation of alcohols to aldehydes and ketones. The present book, which is a Jones reagent, PCC etc., are employed. ? Oxidation of alcohols to carbonyl compound occurs via Cr(VI) acid monoester. Mechanism is as follows. PDF | This review concerns metal-catalyzed reactions of oxidation of alcohols to the respective products, mainly ketones and aldehydes, mostly within. -allylic alcohols are oxidized to ?,?-unsaturated aldehydes. Page 4. OXIDATIONS 8. - Supported Reagents. Comprehensive Organic Synthesis 1991, 7, 839. PCC on Alcohols are more oxidized than alkanes but less oxidized than the corresponding carbonyl compounds such as ketones and aldehydes. The oxidation state oralcohol ketone. OH. R. H. O aldehyde or. Myers. Chem 115. Oxidation DMP precursor IBX is gaining use as a mild reagent for the oxidation of alcohols. 2. Chemoselectivity - oxidation of primary alcohols requires control as there are two potential products: the carboxylic acid or the aldehyde. Aldehydes are Need to be able to control oxidation of primary alcohols so only obtain aldehyde or acid. • Large number of reagents – all have their advantages and