How do surfactants stabilise emulsions

Polym Gels —17 Google Scholar. Cellulose — Google Scholar. Andresen M, Stenius P Water-in-oil emulsions stabilized by hydrophobized microfibrillated cellulose. Pickering emulsions stabilised by Laponite clay particles. Phys Rev Lett — Google Scholar. Aberdeen Google Scholar. Binks BP, Lumsdon SO b Effects of oil type and aqueous phase composition on oil- water mixtures containing particles of intermediate hydrophobicity.

Binks BP Particles as surfactants — similarities and differences. A pendant drop study of interactions between n-dodecyl benzoic acid and divalent cations.

II: formation and stability of metal naphthenate films at oil—water interfaces. Europhys Lett — Google Scholar. Aiche J — Google Scholar. Chesters AK, Bazhlekov IB Effect of insoluble surfactants on drainage and rupture of a film between drops interacting under a constant force. Czarnecki J Asphaltenes and emulsion stabilization. Rio de Janeiro, Brazil. Deo M, Parra M Characterization of carbon-dioxide-induced asphaltene precipitation. Dongming L Coalescence between small bubbles: effects of surface tension gradient and surface viscosities.

J Mater Sci —33 Google Scholar. A light, x-ray, and neutron scattering investigation. Fan Y, Simon S, Sjoblom J Interfacial shear rheology of asphaltenes at oil—water interface and its relation to emulsion stability: influence of concentration, solvent aromaticity and nonionic surfactant. Fenistein D, Barre L Experimental measurement of the mass distribution of petroleum asphaltene aggregates using ultracentrifugation and small-angle X-ray scattering.

Fuel — Google Scholar. Fontell K, Ceglie A, Lindman B, Ninham B Some observations on phase diagrams and structure in binary and ternary systems of didodecyldimethylammonium bromide.

Interfacial tension and solvent properties. Physical and chemical characteristics. Friberg S Liquid crystalline phases in emulsions.

Friberg SE Micellization. Adv Eng Softw — Google Scholar. Goncalves S, Castillo J, Fernandez A, Hung J Absorbance and fluorescence spectroscopy on the aggregation behavior of asphaltene-toluene solutions. Polymer — Google Scholar. Grimes BA Population balance model for batch gravity separation of crude oil and water emulsions.

Part I: model formulation. Journal of Dispersion Science and Technology Accepted for publication. Hahn P-S, Chen J-D, Slattery JC Effects of London-van der waals forces on the thinning and rupture of a dimpled liquid film as a small drop or bubble approaches a fluid-fluid interface. Hahn PS, Slattery JC Effects of surface viscosities on the stability of a draining plane parallel liquid film as a small bubble approaches a liquid—gas interface.

Colloids Surf, A —58 Google Scholar. The effect of dilution. Chem Eng Sci — Google Scholar. Havre TE, Sjoblom J Emulsion stabilization by means of combined surfactant multilayer D-phase and asphaltene particles. Colloids Surf, A — Google Scholar. Influence of non-ionic surfactant addition on the stability and rheology of particle-stabilized emulsions. Continuous synthesis of plate-like silica microparticles using microfluidics.

Journal of Flow Chemistry , 9 3 , RSM optimization of oil-in-water microemulsion stabilized by synthesized zwitterionic surfactant and its properties evaluation for application in enhanced oil recovery.

Chemical Engineering Research and Design , , The effect of silanization assisted nanoparticle hydrophobicity on emulsion stability through droplet size distribution analysis. Chemical Engineering Science , , Part 1: Interplay of SLN and oil droplets. Lubricants , 6 2 , Gavrielatos , R.. Dabirian , R.. Mohan , O.. Nanoparticle stabilized oil in water emulsions: A critical review. Multi-modal stabilisation of emulsions using a combination of hydrophilic particles and an amino acid. Synthesis, characterization, physical and thermodynamic properties of a novel anionic surfactant derived from Sapindus laurifolius.

RSC Advances , 8 43 , Interfacial adsorption of pH-responsive polymers and nanoparticles. Soft Matter , 13 30 , Clegg , Tao Li , Katherine A. Rumble , Joe W. Bijels formed by direct mixing. Soft Matter , 13 28 , International Journal of Biological Macromolecules , 93 , Bulk and interfacial rheology of emulsions stabilized with clay particles.

Efficient demulsification of oil-in-water emulsions using a zeolitic imidazolate framework: Adsorptive removal of oil droplets from water.

Journal of Colloid and Interface Science , , Waste and Biomass Valorization , 6 4 , Pair your accounts. Your Mendeley pairing has expired. Please reconnect. This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy. Find more information about Crossref citation counts. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online.

Clicking on the donut icon will load a page at altmetric. Find more information on the Altmetric Attention Score and how the score is calculated. In classical emulsification processes, surfactants play two roles: first, they reduce the interfacial tension, facilitating droplet deformation and rupture, and second, they reduce droplet coalescence. Here, we use a microfluidic emulsification system to completely uncouple these two processes, allowing stabilization against coalescence to be studied quantitatively and independently of droplet formation.

Microfluidic emulsification devices can therefore be tailored to improve emulsification while decreasing the concentration of surfactant by increasing the time before the droplets first come into contact. Sketch of the optical setup for on-chip fluorescence measurement.

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Haut, A. Pedrono, B. Scheid, D. Langmuir , 34 34 , Langmuir , 34 17 , Helms, Thomas P. ACS Nano , 12 3 , Whitaker , Adam K. Schmitt , and Tzu-Chi Kuo. Langmuir , 33 36 , Langmuir , 32 13 , Patrick Collier , Narayana R. Aluru , and Stephen A. Langmuir , 31 47 , Analytical Chemistry , 87 4 , Weitz , and Jean-Christophe Baret. Langmuir , 31 3 , Frostad , Martha C. Collins , and L. Gary Leal. Langmuir , 29 15 , Dong , H.

Zhao , C. Tostado , and G. Langmuir , 28 25 , Langmuir , 28 15 , Tostado , J. Du , and G. Langmuir , 28 6 , Molecular Pharmaceutics , 8 2 , Analytical Chemistry , 83 6 , Langmuir , 26 18 , Langmuir , 26 11 , Langmuir , 26 9 , Steegmans , Anja Warmerdam , Karin G.

Langmuir , 25 17 , Belousov , N. Filatov , I. Kukhtevich , V. Kantsler , A. Evstrapov , A. An asymmetric flow-focusing droplet generator promotes rapid mixing of reagents.

Coalescence dynamics in oil-in-water emulsions at elevated temperatures. Emulsion characterization via microfluidic devices: A review on interfacial tension and stability to coalescence. Advances in Colloid and Interface Science , 47 ,